Chemical Communications 2008-07-28

Influence of a diene impurity on the molecular structure of phosphate-containing polymers with medical applications.

Lisbeth Grøndahl, Shuko Suzuki, Edeline Wentrup-Byrne

Index: Chem. Commun. (Camb.) (28) , 3314-6, (2008)

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Abstract

We have demonstrated that the unacknowledged presence of almost 30% diene impurity in some commercial phosphate monomers had not only a significant effect on the molecular structure (topology) of a series of synthesized polymers but the instability of the ester functionalities during these polymerizations resulted in unexpectedly complex co-polymer chemistry.