Journal of Organometallic Chemistry

6-Halogenofulvenes and allylcyclopentadiene from nickelocene

C Moberg, M Nilsson

Index: Moberg,C.; Nilsson,M. Journal of Organometallic Chemistry, 1973 , vol. 49, p. 243 - 248

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Citation Number: 23

Abstract

Abstract In the presence of triphenylphosphine, nickelocene reacts with tetrachloromethane to give (trichloromethyl) cyclopentadiene, which can be dehydrohalogenated to 6, 6- dichlorofulvene. It reacts analogously with tetrabromomethane and (trichloromethyl) benzene. 3-Bromopropene reacts with nickelocene to give allylcyclopentadiene.

56-23-5

Carbon tetrachloride

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