Chemical Communications 2007-11-14

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides.

Naoki Ishida, Tomoya Miura, Masahiro Murakami

Index: Chem. Commun. (Camb.) (42) , 4381-3, (2007)

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Abstract

The palladium-catalysed reaction of alkynyltriarylborates with aryl halides afforded trisubstituted alkenylboranes, in which two different aryl groups were installed across the carbon-carbon double bond in a cis arrangement.