Synthetic Communications®

Synthesis of aryl ketones by cross-coupling reaction of arylboronic acids with carboxylic anhydrides in aqueous phase

BW Xin

Index: Xin, Bing-Wei Synthetic Communications, 2008 , vol. 38, # 16 p. 2826 - 2837

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Citation Number: 15

Abstract

Abstract A highly efficient aqueous system of PdCl2-catalyzed cross-coupling reaction of arylboronic acid with carboxylic anhydride (Suzuki-type reaction) without the use of phosphine ligands was developed. The reactions went smoothly in acetone/H2O phase to