e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Tetrahedron
Homolytic chlorination of aliphatic compounds—V: Photochlorination of methylsilanes, methyl (chloromethyl)-silanes, ethylsilanes and their carbon analogues
Y Nagai, M Kosugi, K Takeuchi, T Migita
Index: Nagai,Y. et al. Tetrahedron, 1970 , vol. 26, p. 2791 - 2800
The relative reactivities of various C H bonds of eleven different alkylchlorosilanes in photochlorination were compared with those of the corresponding carbon analogues. Results show that the C H bonds attached to carbon are more activated than would be expected on the basis of the inductive effect only. It is also shown that the relative reactivities of various C H bonds are correlated with the 13C H coupling constants. The Hammett- ...
