4-Bromobenzaldehyde
Names
[ CAS No. ]:
1122-91-4
[ Name ]:
4-Bromobenzaldehyde
[Synonym ]:
p-Bromobenzaldehyde
Benzaldehyde,p-bromo
4-bromo benzaldehyde
Benzaldehyde,4-bromo
Benzaldehyde, 4-bromo-
4-Bromobenzylaldehyde
EINECS 214-365-0
p-Bromo benzaldehyde
4-Bromobenzaldehyde
4-bromobenzylcarboxaldehyde
4-bromophenylcarboxaldehyde
para-bromobenzaldehyde
MFCD00003377
Biological Activity
[Description]:
[Related Catalog]:
[In Vitro]
Chemical & Physical Properties
[ Density]:
1.6±0.1 g/cm3
[ Boiling Point ]:
244.0±23.0 °C at 760 mmHg
[ Melting Point ]:
55-58 °C(lit.)
[ Molecular Formula ]:
C7H5BrO
[ Molecular Weight ]:
185.02
[ Flash Point ]:
108.9±0.0 °C
[ Exact Mass ]:
183.952377
[ PSA ]:
17.07000
[ LogP ]:
2.57
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.611
[ Water Solubility ]:
INSOLUBLE
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CU4810000
- CHEMICAL NAME :
- Benzaldehyde, p-bromo-
- CAS REGISTRY NUMBER :
- 1122-91-4
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C7-H5-Br-O
- MOLECULAR WEIGHT :
- 185.03
- WISWESSER LINE NOTATION :
- VHR DE
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1230 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 389 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H315-H317-H319-H335
[ Precautionary Statements ]:
P280-P301 + P312 + P330-P304 + P340 + P312-P305 + P351 + P338-P333 + P313-P337 + P313
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
Xn:Harmful
[ Risk Phrases ]:
R22
[ Safety Phrases ]:
S26-S36/37-S36/37/39-S22
[ RIDADR ]:
2811
[ WGK Germany ]:
2
[ RTECS ]:
CU4810000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
2913000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2913000090
[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%
Articles
Dalton Trans. 44(2) , 725-32, (2014)
The metastable tetragonal Cu2Se phase as nanoflakes has been synthesized for the first time by treating CuCl2 taken in a mixture (1:1) of 1-octadecene and oleylamine with H2N-(CH2)3-SePh dissolved in ...
Suzuki-Miyaura cross-coupling reactions of potassium vinyltrifluoroborate with aryl and heteroaryl electrophiles.J. Org. Chem. 71 , 9681, (2006)
We have previously reported that the palladium-catalyzed cross-coupling reaction of potassium vinyltrifluoroborate with aryl electrophiles proceeds with good yields. Herein, we describe recent progres...
Tetrahedron Lett. 48 , 539, (2007)