1,2,5,6-cyclooctanetetraylidene, nickel salt
Names
[ CAS No. ]:
1295-35-8
[ Name ]:
1,2,5,6-cyclooctanetetraylidene, nickel salt
[Synonym ]:
EINECS 215-072-0
Bis(cyclooctadiene)nickel Ni(COD)2
1,2,5,6-Cyclooctanetetraylidene - nickel (2:1)
1,2,5,6-cyclooctanetetraylidene, nickel salt
(1Z,5Z)-cycloocta-1,5-diene,nickel
cyclooctane-1,2,5,6-tetraylidene - nickel (2:1)
1,2,5,6-Cyclooctanetetraylidene, nickel salt (2:1)
MFCD00058902
Chemical & Physical Properties
[ Boiling Point ]:
153.5ºC at 760 mmHg
[ Melting Point ]:
60 °C (dec.)(lit.)
[ Molecular Formula ]:
C16H24Ni
[ Molecular Weight ]:
266.992
[ Flash Point ]:
31.7ºC
[ Exact Mass ]:
266.060547
[ LogP ]:
5.34560
[ Vapour Pressure ]:
4.25mmHg at 25°C
[ Storage condition ]:
0-6°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QR6135000
- CHEMICAL NAME :
- Nickel, bis(1,5-cyclooctadiene)-
- CAS REGISTRY NUMBER :
- 1295-35-8
- LAST UPDATED :
- 199410
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C16-H24-Ni
- MOLECULAR WEIGHT :
- 275.11
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 1 mg/plate
- REFERENCE :
- EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 21),2,1992
Safety Information
[ Symbol ]:
GHS02, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H334-H351
[ Precautionary Statements ]:
P210-P261-P281-P342 + P311
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
F:Flammable;T:Toxic;
[ Risk Phrases ]:
R45;R11
[ Safety Phrases ]:
S36/37
[ RIDADR ]:
UN 1325 4.1/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
QR6135000
[ Packaging Group ]:
I
[ Hazard Class ]:
4.2
Synthetic Route
Articles
Dalton Trans. 43(42) , 15997-6005, (2014)
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while main...
Nickel-catalyzed thioallylation of alkynes with allyl phenyl sulfides.Org. Lett. 9 , 263, (2007)
Allylic sulfides add to alkynes in the presence of nickel complexes efficiently to afford thio-1,4-dienes regio- and stereoselectively. Functional groups such as alkoxy, siloxy, hydroxy, carboalkoxy, ...
A boron-doped helicene as a highly soluble, benchtop-stable green emitter.Chem. Commun. (Camb.) 51(87) , 15808-10, (2015)
The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility ...