4-Bromo-N,N-dimethylaniline
Names
[ CAS No. ]:
586-77-6
[ Name ]:
4-Bromo-N,N-dimethylaniline
[Synonym ]:
N-(4-bromophenyl)-N,N-dimethylamine
p-(Dimethylamino)phenyl bromide
N,N-Dimethyl-p-bromoaniline
Benzenamine, 4-bromo-N,N-dimethyl-
Benzenamine,4-bromo-N,N-dimethyl
EINECS 209-582-2
4-Bromo-N,N-dimethylbenzenamine
4-N,N-dimethylaminobromobenzene
MFCD00000093
(4-bromophenyl)dimethylamine
N,N-Dimethyl-4-bromoaniline
1-bromo-4-dimethylaminobenzene
p-Bromo-N,N-dimethylaniline
N,N-(dimethylamino)-4-bromobenzene
p-Dimethylaminobromobenzene
4-Bromo-N,N-dimethylaniline
4-bromo-N,N-dimethyl-aniline
(4-bromo-phenyl)-dimethylamine
4-dimethylamino-1-bromobenzene
4-Dimethylaminobromobenzene
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
264.0±0.0 °C at 760 mmHg
[ Melting Point ]:
52-54 °C(lit.)
[ Molecular Formula ]:
C8H10BrN
[ Molecular Weight ]:
200.076
[ Flash Point ]:
104.7±19.8 °C
[ Exact Mass ]:
198.999649
[ PSA ]:
3.24000
[ LogP ]:
3.34
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.587
[ Stability ]:
Stable. Incompatible with oxidizing agents, acids, metals.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BW9300000
- CHEMICAL NAME :
- Aniline, 4-bromo-N,N-dimethyl-
- CAS REGISTRY NUMBER :
- 586-77-6
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C8-H10-Br-N
- MOLECULAR WEIGHT :
- 200.10
- WISWESSER LINE NOTATION :
- ER DN1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 90,260,1947
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302 + H312 + H332-H315-H319
[ Precautionary Statements ]:
P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful
[ Risk Phrases ]:
R22;R33
[ Safety Phrases ]:
S26-S36-S45-S37-S28A
[ RIDADR ]:
2811
[ WGK Germany ]:
3
[ RTECS ]:
BW9300000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
2921499090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921420090
[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Dalton Trans. 44 , 9847-59, (2015)
Utilization of dioxygen as the terminal oxidant at ambient temperature is always a challenge in redox chemistry, because it is hard to oxidize a stable redox metal ion like iron(III) to its high oxida...
Single drop microextraction or solid phase microextraction-gas chromatography-mass spectrometry for the determination of iodine in pharmaceuticals, iodized salt, milk powder and vegetables involving conversion into 4-iodo-N,N-dimethylaniline.J. Chromatogr. A. 1023(1) , 33-9, (2004)
A rapid sequence of oxidation and iodination using 2-iodosobenzoate as an oxidizing agent and N,N-dimethylaniline as an iodine scavenger at pH 6.4, when 4-iodo-N,N-dimethylaniline is formed, has been ...