Terbuthylazine
Names
[ CAS No. ]:
5915-41-3
[ Name ]:
Terbuthylazine
[Synonym ]:
N2-(tert-Butyl)-6-chloro-N4-ethyl-1,3,5-triazine-2,4-diamine
TERBA
Gardoprim
1,3,5-Triazine-2,4-diamine, 6-chloro-N-(1,1-dimethylethyl)-N-ethyl-
Sorgoprim
MFCD00055513
1,3,5-Triazin-2-amine, 4-chloro-N-(1,1-dimethylethyl)-6-(ethylimino)-1,6-dihydro-, (6E)-
Terbutylazine
N-tert-Butyl-6-chlor-N'-ethyl-1,3,5-triazin-2,4-diamin
N-tert-butyl-6-chloro-N'-ethyl-1,3,5-triazine-2,4-diamine
Terbuthylazine
6-Chloro-N-ethyl-N'-(2-methyl-2-propanyl)-1,3,5-triazine-2,4-diamine
EINECS 227-637-9
6-chloro-N-(1,1-dimethylethyl)-N’-ethyl-1,3,5-triazine-2,4-diamine
N2-tert-butyl-6-chloro-N4-ethyl-1,3,5-triazine-2,4-diamine
(6E)-4-Chloro-6-(ethylimino)-N-(2-methyl-2-propanyl)-1,6-dihydro-1,3,5-triazin-2-amine
Biological Activity
[Description]:
[Related Catalog]:
[References]
[Related Small Molecules]
Chemical & Physical Properties
[ Density]:
1.3±0.1 g/cm3
[ Boiling Point ]:
290.8±23.0 °C at 760 mmHg
[ Melting Point ]:
177-179ºC
[ Molecular Formula ]:
C9H16ClN5
[ Molecular Weight ]:
229.710
[ Flash Point ]:
129.7±22.6 °C
[ Exact Mass ]:
229.109421
[ PSA ]:
62.73000
[ LogP ]:
1.26
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.580
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XY4550000
- CHEMICAL NAME :
- s-Triazine, 2-(tert-butylamino)-4-chloro-6-(ethylamino)-
- CAS REGISTRY NUMBER :
- 5915-41-3
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- C9-H16-Cl-N5
- MOLECULAR WEIGHT :
- 229.75
- WISWESSER LINE NOTATION :
- T6N CN ENJ BMX1&1&1 DG FM2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1845 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,60,1973
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >3510 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A385,1984
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >3 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,797,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Parenteral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2160 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 26,5,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,437,1971
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >3 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C298,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H400
[ Precautionary Statements ]:
P301 + P312 + P330
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
F,T,Xn
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
7-16-24-45-36
[ RIDADR ]:
UN1230 3/PG 2
[ RTECS ]:
XY4550000
[ Packaging Group ]:
I; II; III
[ Hazard Class ]:
6.1
Precursor & DownStream
Precursor
DownStream
Articles
J. Agric. Food Chem. 62(47) , 11449-56, (2014)
This paper describes the comparison of five sample cleanup procedures for the determination of 238 pesticides via triple quadrupole liquid chromatography-tandem mass spectrometry (LC-MS/MS, with only ...
Development of a selective sorbent for the solid-phase extraction of terbuthylazine in olive oil samples: a molecular imprinting strategy.J. Sep. Sci. 38(7) , 1204-12, (2015)
Aiming to implement an analytical methodology that is highly selective for the extraction and quantification of terbuthylazine from olive oil, we successfully achieved: (i) the development of a molecu...
Development of a Matrix Solid Phase Dispersion methodology for the determination of triazine herbicides in mussels.Food Chem. 173 , 391-6, (2014)
A method based on Matrix Solid Phase Dispersion (MSPD) for determination of nine triazines in mussels has been optimised in terms of the sorbents used for extracting and cleaning-up. Two dispersing ag...