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Dimethyl disulfide

Names

[ CAS No. ]:
624-92-0

[ Name ]:
Dimethyl disulfide

[Synonym ]:
Methyldisulfide
Methyl disulphide
dithioether
2,3-Dithiabutane
Methyl disulfide (8CI)
Dimethyldisulfide
(Methyldisulfanyl)methane
Methyldisulfanylmethane
EINECS 210-871-0
Dimethyl disulfide
Disulfide, dimethyl
1,2-dimethyldisulfane
Dimethyl disulphide
(methyldithio)methane
1SS1
Methyldithiomethane
DMDS
MFCD00008561
Disulfide,dimethyl
Methyl disulfide

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
109.7±0.0 °C at 760 mmHg

[ Melting Point ]:
-85 °C

[ Molecular Formula ]:
C2H6S2

[ Molecular Weight ]:
94.199

[ Flash Point ]:
24.4±0.0 °C

[ Exact Mass ]:
93.991089

[ PSA ]:
50.60000

[ LogP ]:
1.77

[ Vapour density ]:
3.24 (vs air)

[ Vapour Pressure ]:
28.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.522

[ Stability ]:
Stable. Incompatible with strong bases, strong oxidizing agents, strong reducing agents. Flammable.

[ Water Solubility ]:
<0.1 g/100 mL at 20 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JO1927500
CHEMICAL NAME :
Disulfide, dimethyl
CAS REGISTRY NUMBER :
624-92-0
LAST UPDATED :
199806
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C2-H6-S2
MOLECULAR WEIGHT :
94.20
WISWESSER LINE NOTATION :
1SS1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
15850 ug/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 16(6),46,1972
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
12300 ug/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 16(6),46,1972
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
138 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 16(6),46,1972 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2126 mg/kg/4W-I
TOXIC EFFECTS :
Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0000696-1
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
13819 mg/kg/16D-I
TOXIC EFFECTS :
Cardiac - other changes Skin and Appendages - dermatitis, other (after systemic exposure) Related to Chronic Data - death
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0000696-1 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5408 No. of Facilities: 14 (estimated) No. of Industries: 3 No. of Occupations: 21 No. of Employees: 3492 (estimated) No. of Female Employees: 272 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H319-H331-H335-H411

[ Precautionary Statements ]:
P210-P261-P273-P280-P304 + P340 + P312-P403 + P233

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R22;R26;R36/37/38;R51/53

[ Safety Phrases ]:
S26-S61-S45-S38-S36/37/39-S28A-S16-S60

[ RIDADR ]:
UN 2381 3/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
JO1927500

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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