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2-Amino-p-xylene

Names

[ CAS No. ]:
95-78-3

[ Name ]:
2-Amino-p-xylene

[Synonym ]:
p-Dimethylaniline
Benzenamine,2,5-dimethyl
EINECS 202-451-0
1-amino-2,5-dimethylbenzene
2,5-di-methyl amino benzene
ZR B1 E1
5-Methyl-o-toluidine
MFCD00007743
2,5-dimethyl-aniline
6-Methyl-m-toluidine
p-Xylidine
2,5-Xylidine
2,5-dimethylbenzeneamine
2-Amino-1,4-dimethylbenzene
2,5-Dimethylaniline
o-amino-p-xylene
Benzenamine, 2,5-dimethyl-
2,5-Dimethylbenzenamine
2-Amino-p-xylene

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
214.9±9.0 °C at 760 mmHg

[ Melting Point ]:
11.5 °C(lit.)

[ Molecular Formula ]:
C8H11N

[ Molecular Weight ]:
121.180

[ Flash Point ]:
93.9±0.0 °C

[ Exact Mass ]:
121.089149

[ PSA ]:
26.02000

[ LogP ]:
1.86

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.559

[ Water Solubility ]:
<0.1 g/100 mL at 18 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZE9100000
CHEMICAL NAME :
2,5-Xylidine
CAS REGISTRY NUMBER :
95-78-3
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C8-H11-N
MOLECULAR WEIGHT :
121.20
WISWESSER LINE NOTATION :
ZR B1 E1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1297 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
841 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
13300 mg/kg/4W-I
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
200 mg/kg
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 46,305,1977 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 16,377,1978 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 16,377,1978 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373-H411

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R23/24/25;R33;R51/53

[ Safety Phrases ]:
S28-S36/37-S45-S61-S28A

[ RIDADR ]:
UN 1711 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
ZE9100000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2921499090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Separation and analysis of dimethylaniline isomers by supercritical fluid chromatography—Electrospray ionization tandem mass spectrometry

J. Chromatogr. A. 1216(41) , 6970-3, (2009)

The assessment of human exposure to specific isomers of dimethylanilines (DMA's) is of interest for the evaluation of potential exposure-health outcome relationships. Improved analytical methods will ...

Determination method for xylidines in workplace air.

J. Occup. Health 53(3) , 230-3, (2011)

The purpose of this research was to develop a determination method for xylidines (XLDs) in workplace air for risk assessment.The characteristics of the proposed method, such as recovery, detection lim...

Oxidation of 2, 5-dimethylaniline in NH 4 F· 2.35 HF medium Characteristics of the resulting conducting polymer. Genies EM and Noel P.

J. Electroanal. Chem. Interfac. Electrochem. 296(2) , 473-490, (1990)


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