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65076-02-0

65076-02-0 structure
65076-02-0 structure
  • Name: DIETHYL 2-[(3-THIENYLAMINO)METHYLIDENE!MALONATE+
  • Chemical Name: diethyl 2-[(thiophen-3-ylamino)methylidene]propanedioate
  • CAS Number: 65076-02-0
  • Molecular Formula: C12H15NO4S
  • Molecular Weight: 269.31700
  • Create Date: 2018-12-31 21:10:18
  • Modify Date: 2024-01-10 18:47:25

Name diethyl 2-[(thiophen-3-ylamino)methylidene]propanedioate
Synonyms MFCD00122043
Molecular Formula C12H15NO4S
Molecular Weight 269.31700
Exact Mass 269.07200
PSA 92.87000
LogP 2.24310
Name: Diethyl 2-[(3-thienylamino)methylidene]malonate Material Safety Data Sheet
Synonym:
CAS: 65076-02-0
Section 1 - Chemical Product MSDS Name:Diethyl 2-[(3-thienylamino)methylidene]malonate Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
65076-02-0 Diethyl 2-[(3-thienylamino)methylidene 97+% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 65076-02-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 83 - 86 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H15NO4S
Molecular Weight: 269.32

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Not available.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 65076-02-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diethyl 2-[(3-thienylamino)methylidene]malonate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 65076-02-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 65076-02-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 65076-02-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
HS Code 2934999090

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65076-02-0

Literature: Larsen, Scott D.; May, Paul; Romines, Karen; Schnute, Mark E.; Tanis, Steven P. Patent: US2004/138449 A1, 2004 ; Location in patent: Page 17 ;

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65076-02-0

Literature: Malicorne; Bompart; Giral; Despaux European Journal of Medicinal Chemistry, 1991 , vol. 26, # 1 p. 3 - 11

~48%

65076-02-0 structure

65076-02-0

Literature: Elliot, Richard, L.; O'Hanlon, Peter J.; Rogers, Norman H. Tetrahedron, 1987 , vol. 43, # 14 p. 3295 - 3302

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65076-02-0 structure

65076-02-0

Literature: Barker, John M.; Huddleston, Patrick R.; Keenan, Guy J. Journal of Chemical Research, Miniprint, 1982 , # 6 p. 1726 - 1746

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65076-02-0 structure

65076-02-0

Literature: Fernandez, Maria-Carmen; Escribano, Ana; Mateo, Ana I.; Parthasarathy, Saravanan; Martin De La Nava, Eva M.; Wang, Xiaodong; Cockerham, Sandra L.; Beyer, Thomas P.; Schmidt, Robert J.; Cao, Guoqing; Zhang, Youyan; Jones, Timothy M.; Borel, Anthony; Sweetana, Stephanie A.; Cannady, Ellen A.; Stephenson, Gregory; Frank, Scott; Mantlo, Nathan B. Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 9 p. 3056 - 3062
HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%