Name | tert-butyl benzenecarbodithioate |
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Synonyms |
tert-butyl dithiobenzoate
Dithiobenzoesaeure-tert.butylester Benzenecarbodithioic acid,1,1-dimethylethyl ester |
Molecular Formula | C11H14S2 |
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Molecular Weight | 210.35900 |
Exact Mass | 210.05400 |
PSA | 57.39000 |
LogP | 3.89380 |
Storage condition | 2-8°C |
Section 1: Product Identification Chemical Name:2-Methyl-2-propylbenzodithiolate CAS Registry Number:5925-55-3 Formula:C11H14S2 EINECS Number:none Chemical Family:organosulfur compound Synonym:none
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound5925-55-3100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Inhalation, skin, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Store cold, in a tightly sealed container. Material is light sensitive. Prolonged exposure may degrade the Handling and Storage: material. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:red-orange liq Molecular Weight:210.36 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:rotten egg odor Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable, light sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged exposure to light Incompatibility:oxidizing agents and halogens Decomposition Products:carbon monoxide, carbon dioxide, sulfur oxides and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Not reportable under SARA 313 Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
HS Code | 2930909090 |
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~89% 5925-55-3 |
Literature: Chernikova, Elena; Morozov, Audrey; Leonova, Ekaterina; Garina, Elizaveta; Golubev, Vladimir; Bui, Chuong; Charleux, Bernadette Macromolecules, 2004 , vol. 37, # 17 p. 6329 - 6339 |
~68% 5925-55-3 |
Literature: Sudalai, Arumugam; Kanagasabapathy, Subbareddy; Benicewicz, Brian C. Organic Letters, 2000 , vol. 2, # 20 p. 3213 - 3216 |
~46% 5925-55-3 |
Literature: Sudalai, Arumugam; Kanagasabapathy, Subbareddy; Benicewicz, Brian C. Organic Letters, 2000 , vol. 2, # 20 p. 3213 - 3216 |
~65% 5925-55-3 |
Literature: Chong, Bill Y. K.; Krstina, Julia; Le, Tam P.T.; Moad, Graeme; Postma, Almar; Rizzardo, Ezio; Thang, San H. Macromolecules, 2003 , vol. 36, # 7 p. 2256 - 2272 |
~66% 5925-55-3 |
Literature: E.I. DU PONT DE NEMOURS AND COMPANY; COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION Patent: EP910587 B1, 2001 ; |
~64% 5925-55-3 |
Literature: Drosten, Gisela; Mischke, Peter; Voss, Juergen Chemische Berichte, 1987 , vol. 120, p. 1757 - 1762 |
~% 5925-55-3 |
Literature: Chong, Bill Y. K.; Krstina, Julia; Le, Tam P.T.; Moad, Graeme; Postma, Almar; Rizzardo, Ezio; Thang, San H. Macromolecules, 2003 , vol. 36, # 7 p. 2256 - 2272 |
~52% 5925-55-3 |
Literature: Kato, Shinzi; Shibahashi, Hiroshi; Katada, Tomonori; Takagi, Takashi; Noda, Ippei; et al. Liebigs Annalen der Chemie, 1982 , # 7 p. 1229 - 1244 |
~% 5925-55-3 |
Literature: Mayer,R. et al. Chemische Berichte, 1966 , vol. 99, p. 1393 - 1413 |
HS Code | 2930909090 |
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Summary | 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |