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2396-77-2

2396-77-2 structure
2396-77-2 structure

Name Methyl 2-hexenoate
Synonyms hex-2-enoic acid methyl ester
2-Hexenoic acid methyl
FEMA 2709
2-Hexenoic Acid Methyl Ester
Hex-2-ensaeure-methylester
METHYL TRANS-2-HEXENOATE
MFCD00048798
METHYL T2 HEXENOATE
methyl hex-2-enoate
Density 0.907 g/cm3
Boiling Point 149.3ºC at 760 mmHg
Molecular Formula C7H12O2
Molecular Weight 128.16900
Flash Point 45.4ºC
Exact Mass 128.08400
PSA 26.30000
LogP 1.51570
Vapour Pressure 4.06mmHg at 25°C
Index of Refraction 1.427
Material Safety Data Sheet

Section1. Identification of the substance
Product Name: Methyl 2-hexenoate
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H226:Flammable liquid and vapour
P210:Keep away from heat/sparks/open flames/hot surfaces. No smoking
P280:Wear protective gloves/protective clothing/eye protection/face protection
P240:Ground/bond container and receiving equipment
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower
P403+P235:Store in a well ventilated place. Keep cool

Section3. Composition/information on ingredients.
Ingredient name:Methyl 2-hexenoate
CAS number:2396-77-2

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels, refrigerated.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
No data
Boiling point:
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C7H12O2
Molecular weight: 128.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN3272Class: 3Packing group: III
Proper shipping name: ESTERS, N.O.S. (Methyl 2-hexenoate)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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Detail
Literature: EP1222157 B1, ; Page 4-5 ;

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Literature: TAKEDA PHARMACEUTICAL COMPANY LIMITED Patent: WO2006/36024 A1, 2006 ; Location in patent: Page/Page column 141-142 ;

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Literature: Journal of the American Chemical Society, , vol. 69, p. 301

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Literature: Journal of the American Chemical Society, , vol. 69, p. 301

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Literature: Synthetic Communications, , vol. 14, # 2 p. 169 - 178

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Literature: Synthetic Communications, , vol. 14, # 2 p. 169 - 178

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Literature: Journal of Organic Chemistry, , vol. 12, p. 138,152

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Literature: Bulletin of the Chemical Society of Japan, , vol. 52, # 1 p. 184 - 185