chloro-tri(propan-2-yl)stannane

Synonym:Chlorotriisopropylstannane, Chlorotriisopropyltin

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound14101-95-2100%0.1mg/m3 (Sn-org)0.1mg/m3 (Sn-org)

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Section 3: Hazards Identification
Emergency Overview:Toxic if swallowed. Severe irritant by inhalation and in contact with skin.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:May cause severe irritation to the eyes.
Skin Contact:May causes severe irritation of the skin.
Forms hydrogen chloride upon exposure to the atmosphere. Inhalation may lead to irritation of the respiratory
Inhalation:
tract.
Ingestion:Toxic if swallowed.
Toxic by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory tract.
Acute Health Affects:
May cause eye and skin burns, dyspnea (breathing difficulty) and pulmonary edema.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit hydrochloric acid fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

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SECTION 7: Handling and Storage
Store material in a tightly sealed container away from moisture. If possible, handle material in an efficient fume
Handling and Storage:
hood. Prolonged exposure to the atmosphere will lead to degradation of the product.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:colorless liquid
Molecular Weight:283.43
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

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SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, hydrochloric acid, organic fumes, and tin oxychlorides.

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SECTION 11: Toxicological Information
RTECS Data:Oral(rat); LD50: 44mg/kg.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Ecological Information:Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

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SECTION 13: Disposal Considerations
Disposal:Avoid release to the environment. Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Organotin compounds, Liquid, N.O.S.
Hazard Class (CFR):6.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 2788
Shipping Name (IATA):Organotin compound, Liquid, N.O.S.
Hazard Class (IATA):6.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 2788

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SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

MOLECULAR FORMULA :

C9-H21-Cl-Sn

MOLECULAR WEIGHT :

283.44

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

44 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 37,801,1982