(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one

Modify Date: 2024-01-01 21:50:36

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure
(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one structure
 Common Name (3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one
CAS Number 145451-95-2 Molecular Weight 343.53400
Density 1.064g/cm3 Boiling Point 438.025ºC at 760 mmHg
Molecular Formula C17H33NO4Si Melting Point N/A
MSDS N/A Flash Point 218.71ºC

 Names

Name (1S,6R,7S,7aS)-7a-[[tert-butyl(dimethyl)silyl]oxymethyl]-7-hydroxy-6-methyl-1-propan-2-yl-1,3,6,7-tetrahydropyrrolo[1,2-c][1,3]oxazol-5-one

 Chemical & Physical Properties

Density 1.064g/cm3
Boiling Point 438.025ºC at 760 mmHg
Molecular Formula C17H33NO4Si
Molecular Weight 343.53400
Flash Point 218.71ºC
Exact Mass 343.21800
PSA 59.00000
LogP 2.53640
Vapour Pressure 0mmHg at 25°C
Index of Refraction 1.496

 Synthetic Route

(4R,5S)-3-benzyl-4-(((tert-butyldimethylsilyl)oxy)methyl)-5-isopropyloxazolidine-4-carbaldehyde structure

(4R,5S)-3-benzy...

CAS#:145484-22-6

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
tert-Butyldimethylsilyl chloride structure

tert-Butyldimet...

CAS#:18162-48-6

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
METHYL (2R,3S)-2-BENZYLAMINO-3-HYDROXY-2-HYDROXYMETHYL-4-METHYLPENTANOATE structure

METHYL (2R,3S)-...

CAS#:145451-91-8

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
methyl (2R,4R)-3-benzyl-2-tert-butyl-4-[(1S)-1-hydroxy-2-methylpropyl]-1,3-oxazolidine-4-carboxylate structure

methyl (2R,4R)-...

CAS#:145451-90-7

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
(4R,5S)-N-Benzyl-4-(t-butyldimethylsilyloxymethyl)-4-hydroxymethyl-5-isopropyloxazoladine structure

(4R,5S)-N-Benzy...

CAS#:145452-01-3

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
methyl (4R,5S)-3-benzyl-4-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-propan-2-yl-1,3-oxazolidine-4-carboxylate structure

methyl (4R,5S)-...

CAS#:145451-93-0

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Reichard, Gregory A. Journal of the American Chemical Society, 1992 , vol. 114, # 26 p. 10677 - 10678
(2R,3S)-methyl 3-((4S,5S)-3-benzyl-4-(((tert-butyldimethylsilyl)oxy)methyl)-5-isopropyloxazolidin-4-yl)-3-hydroxy-2-methylpropanoate structure

(2R,3S)-methyl ...

CAS#:203934-88-7

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey; Li, Weidong; Reichard, Gregory A. Journal of the American Chemical Society, 1998 , vol. 120, # 10 p. 2330 - 2336
(R)-1,2,2-triphenyl-2-((trimethylsilyl)oxy)ethyl (2R,3S)-3-((4S,5S)-3-benzyl-4-(((tert-butyldimethylsilyl)oxy)methyl)-5-isopropyloxazolidin-4-yl)-3-hydroxy-2-methylpropanoate structure

(R)-1,2,2-triph...

CAS#:154226-59-2

~%

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one Structure

(3R,4S,5S,6S)-1...

CAS#:145451-95-2

Literature: Corey, E. J.; Reichard, Gregory, A.; Kania, Robert Tetrahedron Letters, 1993 , vol. 34, # 44 p. 6977 - 6980
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(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one suppliers

(3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one price

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Chemsrc provides CAS#:145451-95-2 MSDS, density, melting point, boiling point, structure, etc. Its name is (3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one>> amp version: (3R,4S,5S,6S)-1-Aza-5-(t-butyldimethylsilyloxymethyl)-4-hydroxy-6-isopropyl-3-methyl-7-oxabicyclo[3.3.0]-octan-2-one

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