Sodium benzenesulfonothioate

Modify Date: 2025-08-21 08:07:33

Sodium benzenesulfonothioate Structure
Sodium benzenesulfonothioate structure
Common Name Sodium benzenesulfonothioate
CAS Number 1887-29-2 Molecular Weight 196.223
Density N/A Boiling Point 335.4ºC at 760mmHg
Molecular Formula C6H5NaO2S2 Melting Point 275ºC (dec.)(lit.)
MSDS Chinese USA Flash Point 156.7ºC

 Names

Name sodium,oxido-oxo-phenyl-sulfanylidene-λ6-sulfane
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 335.4ºC at 760mmHg
Melting Point 275ºC (dec.)(lit.)
Molecular Formula C6H5NaO2S2
Molecular Weight 196.223
Flash Point 156.7ºC
Exact Mass 195.962860
PSA 80.60000
LogP 2.43850
Vapour Pressure 4.72E-05mmHg at 25°C
Index of Refraction 1.655

 MSDS

Name: Benzenethionosulfonic acid sodium salt Material Safety Data Sheet
Synonym:
CAS: 1887-29-2
Section 1 - Chemical Product MSDS Name:Benzenethionosulfonic acid sodium salt Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1887-29-2 Benzenethionosulfonic acid, sodium sal 217-558-8
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1887-29-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 275 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H5NaO2S2
Molecular Weight: 196.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1887-29-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzenethionosulfonic acid, sodium salt - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1887-29-2: No information available.
Canada
CAS# 1887-29-2 is listed on Canada's NDSL List.
CAS# 1887-29-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1887-29-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2930909090

 Synthetic Route

~99%

Sodium benzenesulfonothioate Structure

Sodium benzenes...

CAS#:1887-29-2

Literature: Sato, Ryu; Goto, Takehiko; Takikawa, Yuji; Takizawa, Saburo Synthesis, 1980 , # 8 p. 615

~90%

Sodium benzenesulfonothioate Structure

Sodium benzenes...

CAS#:1887-29-2

Literature: ISIS INNOVATION LIMITED Patent: WO2005/862 A2, 2005 ; Location in patent: Page/Page column 38 ;

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
The catalytic mechanism of yeast thiosulfate reductase.

J. Biol. Chem. 258(24) , 15037-45, (1983)

Thiosulfate reductase catalyzes the desulfuration of thiosulfonates while oxidizing GSH to GSSG. Kinetic studies of the enzyme-catalyzed reaction between GSH and benzenethiosulfonate have been carried...

 Synonyms

Sodium benzenesulfonothioate
Benzene sulfonic acid,thio-,sodium salt
benzenethiosulfonic acid,sodium-salt
MFCD00145297
EINECS 217-558-8
Sodium benzenethiosulfonate
Benzenesulfonothioic acid, sodium salt
Sodium thiobenzosulfonate
Benzenethionosulfonic acid sodium salt
sodium phenylthiosulfonate
Benzenesulfonothioic acid, sodium salt (1:1)
Benzolthiosulfonsaeure,Natrium-Salz
Benzenethiosulfonic acid
Sodium benzene thiosulphonate
sodium benzenethiolsulfonate
Benzenesulfonothioic acid,sodium salt
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