D-Camphorsulfonic acid

Modify Date: 2024-01-02 09:46:28

D-Camphorsulfonic acid Structure
D-Camphorsulfonic acid structure
Common Name D-Camphorsulfonic acid
CAS Number 3144-16-9 Molecular Weight 232.297
Density 1.3±0.1 g/cm3 Boiling Point N/A
Molecular Formula C10H16O4S Melting Point 195ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name camphorsulfonic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Melting Point 195ºC
Molecular Formula C10H16O4S
Molecular Weight 232.297
Exact Mass 232.076935
PSA 79.82000
LogP -0.57
Index of Refraction 1.540

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED1550000
CHEMICAL NAME :
10-Bornanesulfonic acid, 2-oxo-, (1S,4R)-(+)-
CAS REGISTRY NUMBER :
3144-16-9
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H16-O4-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2502 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 1,150,1946

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S25-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS ED1550000
Packaging Group III
Hazard Class 8.0
HS Code 29147090

 Synthetic Route

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D-Camphorsulfonic acid Structure

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CAS#:3144-16-9

Literature: Annali di Chimica Applicata, , vol. 30, p. 284,290 Organic Syntheses, , vol. 45, p. 12

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D-Camphorsulfonic acid Structure

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CAS#:3144-16-9

Literature: Chemische Berichte, , vol. 42, p. 3136

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D-Camphorsulfonic acid Structure

D-Camphorsulfon...

CAS#:3144-16-9

Literature: Analytical Chemistry, , vol. 86, # 2 p. 1282 - 1290

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D-Camphorsulfonic acid Structure

D-Camphorsulfon...

CAS#:3144-16-9

Literature: Bulletin de la Societe Chimique de France, , vol. <3>19, p. 125

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D-Camphorsulfonic acid Structure

D-Camphorsulfon...

CAS#:3144-16-9

Literature: Tetrahedron: Asymmetry, , vol. 6, # 1 p. 43 - 46

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D-Camphorsulfonic acid Structure

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CAS#:3144-16-9

Detail
Literature: Journal of the American Chemical Society, , vol. 47, p. 1172 Organic Syntheses, , vol. 17, p. 80

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D-Camphorsulfonic acid Structure

D-Camphorsulfon...

CAS#:3144-16-9

Literature: Journal of the Society of Chemical Industry, London, , vol. 47, p. 11 T Chem. Zentralbl., , vol. 99, # I p. 2374 Journal of the Society of Chemical Industry, London, , vol. 44, # 497 p. 498 T Chem. Zentralbl., , vol. 97, # I p. 914

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D-Camphorsulfonic acid Structure

D-Camphorsulfon...

CAS#:3144-16-9

Literature: Ann. Chim. applic., , vol. 30, p. 284,288, 289

 Customs

HS Code 2914299000
Summary 2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles26

More Articles
Salt Stability - The Effect of pHmax on Salt to Free Base Conversion.

Pharm. Res. 32 , 3110-8, (2015)

The aim of this study was to investigate how the disproportionation process can be impacted by the properties of the salt, specifically pHmax.Five miconazole salts and four sertraline salts were selec...

Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.

J. Mass Spectrom. 45(12) , 1394-401, (2010)

Chemically modified silicon nanoparticles were applied for the laser desorption/negative ionization of small acids. A series of substituted sulfonic acids and fatty acids was studied. Compared to deso...

Camphorsulfonic acid catalysed facile tandem double Friedlander annulation protocol for the synthesis of phenoxy linked bisquinoline derivatives and discovery of antitubercular agents.

Bioorg. Med. Chem. Lett. 22 , 1643-8, (2012)

A series of phenoxy linked bisquinoline derivatives were synthesised from the Friedlander annulation of 2-(4-acetylphenoxy)-1-aryl-1-ethanones with 2-aminobenzophenone in good yields using (±)-camphor...

 Synonyms

10-Bornanesulfonic acid, 2-oxo-, (1S,4R)-(+)-
b-Camphorsulfonic Acid
UNII:D8D049375Q
D-CAMPHORSULFONIC ACID
(1S)-Camphor-10-sulfonic acid
D-(+)-10-Camphorsulfonic Acid
(+)-Camphor-w-sulfonic Acid
(+)-D-Camphor-10-sulfonic Acid
CSA
camphersulfosaeure
Camphorsulfonic acid
Camphostyl
(1S)-(+)-CAMPHOR-10-SULPHONIC ACIDCamphorSulfonic Acid
EINECS 221-554-1
D-Camphor-10-Sulfonic Acid
Bicyclo(2.2.1)heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
MFCD00064157
(1S)-(+)-10-Camphors
(+)-b-Camphorsulfonic Acid
(+)-(S)-Camphor-10-sulfonic Acid
(1S,4R)-(+)-2-Oxo-10-bornanesulfonic Acid
[(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonic acid
((1S,4R)-7,7-Dimethyl-2-oxobicyclo-[2.2.1]heptan-1-yl)methanesulfonic acid
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic Acid
(1S)-(+)-CSA
D-CAMPHORSULPHONIC ACID
D(+)-10-Camphorsulfonic acid
(S)-10-camphorsulphonic acid
D-10-CAMPHORSULFONIC ACID
10-Camphorsulfonic acid
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid
Reychler's acid
(+)-10-Camphorsulfonic Acid
(+)-Camphor-10-sulfonic acid (β)
(+)-camphorsulfonicacid
D-REYCHLER'S ACID
(1S)-(+)-10-Camphorsulfonic acid
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