2,7-Naphthalenedicarbonitrile

Modify Date: 2024-01-06 18:46:21

2,7-Naphthalenedicarbonitrile Structure
2,7-Naphthalenedicarbonitrile structure
Common Name 2,7-Naphthalenedicarbonitrile
CAS Number 39718-11-1 Molecular Weight 178.18900
Density 1.23g/cm3 Boiling Point 391.6ºC at 760 mmHg
Molecular Formula C12H6N2 Melting Point 267ºC
MSDS N/A Flash Point 198.8ºC

 Names

Name 2,7-Dicyanonaphthalene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.23g/cm3
Boiling Point 391.6ºC at 760 mmHg
Melting Point 267ºC
Molecular Formula C12H6N2
Molecular Weight 178.18900
Flash Point 198.8ºC
Exact Mass 178.05300
PSA 47.58000
LogP 2.58316
Index of Refraction 1.663

 MSDS

2,7-Dicyanonaphthalene
SAFETY DATA SHEET

Section1. IDENTIFICATION
Product name:2,7-Dicyanonaphthalene

Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS
Acute toxicity (Oral)Category 3
Category 3
Acute toxicity (Dermal)
Acute toxicity (Inhalation)Category 3
Category 2
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 2A
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal wordDanger
Toxic if swallowed, in contact with skin or if inhaled
Hazard statements
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Avoid breathing dust/fume/gas/mist/vapours/spray.
[Prevention]
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Wear protective gloves and eye/face protection.
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse
mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Remove/Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
Call a POISON CENTER or doctor/physician if you feel unwell.
2,7-Dicyanonaphthalene

Section2. HAZARDS IDENTIFICATION
[Storage]Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government.

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:2,7-Dicyanonaphthalene
>94.0%(GC)
Percent:
CAS Number:39718-11-1
2,7-Naphthalenedicarbonitrile
Synonyms:
Chemical Formula:C12H6N2

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Immediately call a POISON CENTER or doctor/physician. Rinse mouth.
Ingestion:
Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Dry chemical, foam, water spray, carbon dioxide.
Suitable extinguishing
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical:generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
When extinguishing fire, be sure to wear personal protective equipment.
Special protective
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep
protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
emergency procedures: be controlled around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a closed system if possible. Use a local exhaust if dust or aerosol will be
generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Store in a cool, dark and well-ventilated place.
Storage conditions:
2,7-Dicyanonaphthalene

Section7. HANDLING AND STORAGE
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Packaging material:Comply with laws.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
etc. Use respirators approved under appropriate government standards and follow
local and national regulations.
Hand protection:Impervious gloves.
Eye protection:Safety goggles. A face-shield, if the situation requires.
Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:Crystal- Powder
Colour:Slightly pale yellow - Yellow
Odour:No data available
pH: No data available
Melting point/freezing point:267°C
Boiling point/range:No data available
Flash point:No data available
Flammability or explosive
limits:
No data available
Lower:
Upper:No data available
No data available
Relative density:
Solubility(ies):
[Water]No data available
[Other solvents]No data available

Section10. STABILITY AND REACTIVITY
Stable under proper conditions.
Chemical stability:
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
products:

Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
No data available
Crustacea:
Algae:No data available
2,7-Dicyanonaphthalene

Section12. ECOLOGICAL INFORMATION
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
Log Pow:No data available
No data available
Soil adsorption (Koc):
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:6.1: Toxic substance.
3439
UN-No:
Proper shipping name:Nitriles, solid, toxic, n.o.s.
III
Packing group:

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Synthetic Route

~%

2,7-Naphthalenedicarbonitrile Structure

2,7-Naphthalene...

CAS#:39718-11-1

Literature: Honzawa, Shinobu; Okubo, Hitoshi; Nakamura, Keiichi; Anzai, Shuzo; Yamaguchi, Masahiko; Kabuto, Chizuko Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1043 - 1052

~%

2,7-Naphthalenedicarbonitrile Structure

2,7-Naphthalene...

CAS#:39718-11-1

Literature: Honzawa, Shinobu; Okubo, Hitoshi; Nakamura, Keiichi; Anzai, Shuzo; Yamaguchi, Masahiko; Kabuto, Chizuko Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1043 - 1052

~%

2,7-Naphthalenedicarbonitrile Structure

2,7-Naphthalene...

CAS#:39718-11-1

Literature: Honzawa, Shinobu; Okubo, Hitoshi; Nakamura, Keiichi; Anzai, Shuzo; Yamaguchi, Masahiko; Kabuto, Chizuko Tetrahedron Asymmetry, 2002 , vol. 13, # 10 p. 1043 - 1052

~%

2,7-Naphthalenedicarbonitrile Structure

2,7-Naphthalene...

CAS#:39718-11-1

Literature: Bradbrook; Linstead Journal of the Chemical Society, 1936 , p. 1739 Full Text Show Details King; Wright Journal of the Chemical Society, 1939 , p. 253,256

~%

2,7-Naphthalenedicarbonitrile Structure

2,7-Naphthalene...

CAS#:39718-11-1

Literature: King; Wright Journal of the Chemical Society, 1939 , p. 253,256

 Synonyms

naphthalene-2,7-dicarbonitrile
2,7-Naphthalenedicarbonitrile
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