(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine

Modify Date: 2024-01-04 19:26:51

(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine Structure
(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine structure
Common Name (R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
CAS Number 415918-91-1 Molecular Weight 624.53500
Density N/A Boiling Point 710.7ºC at 760 mmHg
Molecular Formula C37H32Cl2NO2P Melting Point 102-103ºC
MSDS N/A Flash Point 383.6ºC

 Names

Name (s)-(+)-(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1r)-1-phenylethyl]amine,dichloromethane adduct
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 710.7ºC at 760 mmHg
Melting Point 102-103ºC
Molecular Formula C37H32Cl2NO2P
Molecular Weight 624.53500
Flash Point 383.6ºC
Exact Mass 623.15500
PSA 29.52000
LogP 12.47830

 MSDS


Section 1: Product Identification
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,
Chemical Name:
dichloromethane adduct, min. 95%
CAS Registry Number:415918-91-1
Formula:C36H30NO2P
EINECS Number:none
Chemical Family:Phosphoramidite
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound415918-91-1100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes, inhalation
Eye Contact:Causes moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:May be harmful if swallowed. No specific information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Keep material in a tightly sealed container. Prolonged exposure to moisture will result in degradation of the
Handling and Storage:
product. Handle and store material under a dry atmosphere.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:539.6
Melting Point:102-103°
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:reacts slowly with water

SECTION 10: Stability and Reactivity
Stability:air stable, moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:extended exposure to moisture and acids
Incompatibility:oxidizing agents
Decomposition Products:carbon monoxide, phosphorus pentoxide, nitrogen and nitrogen oxides, and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Synonyms

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
MFCD08561138
(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1
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