(S)-n-boc-azetidinecarboxylic acid

Modify Date: 2024-01-03 05:12:10

(S)-n-boc-azetidinecarboxylic acid Structure
(S)-n-boc-azetidinecarboxylic acid structure
Common Name (S)-n-boc-azetidinecarboxylic acid
CAS Number 51077-14-6 Molecular Weight 201.22
Density 1.2±0.1 g/cm3 Boiling Point 321.0±35.0 °C at 760 mmHg
Molecular Formula C9H15NO4 Melting Point 105-110 °C
MSDS Chinese USA Flash Point 147.9±25.9 °C
Symbol GHS07
GHS07
Signal Word Warning

 Use of (S)-n-boc-azetidinecarboxylic acid


(S)-1-(tert-Butoxycarbonyl)azetidine-2-carboxylic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name 1-Boc-L-azetidine-2-carboxylic acid
Synonym More Synonyms

 (S)-n-boc-azetidinecarboxylic acid Biological Activity

Description (S)-1-(tert-Butoxycarbonyl)azetidine-2-carboxylic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 321.0±35.0 °C at 760 mmHg
Melting Point 105-110 °C
Molecular Formula C9H15NO4
Molecular Weight 201.22
Flash Point 147.9±25.9 °C
Exact Mass 201.100113
PSA 66.84000
LogP 0.29
Vapour Pressure 0.0±1.5 mmHg at 25°C
Index of Refraction 1.510
Storage condition Store at -15°C

 MSDS

Name: (S)-N-BOC-Azetidine Carboxylic Acid 95% (98% E.E.) Material Safety Data Sheet
Synonym: (S)-N-tert-Butoxycarbonyl-Azetidine-2-Carboxylic Acid
CAS: 51077-14-6
Section 1 - Chemical Product MSDS Name:(S)-N-BOC-Azetidine Carboxylic Acid 95% (98% E.E.) Material Safety Data Sheet
Synonym:(S)-N-tert-Butoxycarbonyl-Azetidine-2-Carboxylic Acid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
51077-14-6 (S)-N-BOC-Azetidine Carboxylic Acid 95% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 51077-14-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H15NO4
Molecular Weight: 201.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 51077-14-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(S)-N-BOC-Azetidine Carboxylic Acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 51077-14-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 51077-14-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 51077-14-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3

 Synonyms

1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2-azetidinecarboxylic acid
(S)-N-BOC-Azetidine-2-carboxylic acid
1,2-Azetidinedicarboxylic acid, 1-(1,1-dimethylethyl) ester
AZETIDINE-1,2-DICARBOXYLIC ACID 1-TERT-BUTYL ESTER
(S)-1-(tert-Butoxycarbonyl)azetidine-2-carboxylic acid
1-Boc-(S)-Azetidine-2-Carboxylic Acid
(2S)-1-[(2-methylpropan-2-yl)oxycarbonyl]azetidine-2-carboxylic acid
1-(tert-Butoxycarbonyl)azetidine-2-carboxylic acid
MFCD01321011
(S)-n-boc-azetidinecarboxylic acid
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