2,2μ-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide]
Modify Date: 2024-01-02 12:36:17
![2,2μ-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide] Structure](https://image.chemsrc.com/caspic/083/615257-74-4.png)
2,2μ-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide] structure
|
Common Name | 2,2μ-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide] | ||
|---|---|---|---|---|
| CAS Number | 615257-74-4 | Molecular Weight | 742.80000 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C46H39N4O4P | Melting Point | 258-262 °C | |
| MSDS | USA | Flash Point | N/A | |
| Name | (R,R,S)-DiazaPhos-PPE |
|---|---|
| Synonym | More Synonyms |
| Melting Point | 258-262 °C |
|---|---|
| Molecular Formula | C46H39N4O4P |
| Molecular Weight | 742.80000 |
| Exact Mass | 742.27100 |
| PSA | 122.77000 |
| LogP | 9.20960 |
| RIDADR | NONH for all modes of transport |
|---|
|
Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.
J. Am. Chem. Soc. 127 , 5040, (2005) Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaph... |
|
|
Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.
Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)
|
| 2-[(1R,3R)-5,10-dioxo-2-phenyl-3-[2-[[(1S)-1-phenylethyl]carbamoyl]phenyl]-1,3-dihydro-[1,2,4]diazaphospholo[1,2-b]phthalazin-1-yl]-N-[(1S)-1-phenylethyl]benzamide |