Hexanoic acid,2-hydroxyethyl ester

Modify Date: 2024-01-08 22:33:46

Hexanoic acid,2-hydroxyethyl ester Structure
Hexanoic acid,2-hydroxyethyl ester structure
Common Name Hexanoic acid,2-hydroxyethyl ester
CAS Number 6946-90-3 Molecular Weight 160.21100
Density 0.991g/cm3 Boiling Point 253.6ºC at 760 mmHg
Molecular Formula C8H16O3 Melting Point N/A
MSDS N/A Flash Point 102.4ºC

 Names

Name Ethylene glycol monohexanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.991g/cm3
Boiling Point 253.6ºC at 760 mmHg
Molecular Formula C8H16O3
Molecular Weight 160.21100
Flash Point 102.4ºC
Exact Mass 160.11000
PSA 46.53000
LogP 1.10220
Index of Refraction 1.438

 MSDS

Name: Ethyl DL-2-Hydroxycaproate 97% Material Safety Data Sheet
Synonym:
CAS: 6946-90-3
Section 1 - Chemical Product MSDS Name:Ethyl DL-2-Hydroxycaproate 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6946-90-3 Ethyl DL-2-Hydroxycaproate 97 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6946-90-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 195.0 - 195.0 deg C @ 760.00m
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9670g/cm3
Molecular Formula: C8H16O3
Molecular Weight: 160.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6946-90-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl DL-2-Hydroxycaproate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6946-90-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6946-90-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6946-90-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2915900090

 Synthetic Route

~90%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Curini, Massimo; Epifano, Francesco; Marcotullio, Maria Carla; Rosati, Ornelio Synlett, 1999 , # 6 p. 777 - 779

~34%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Hashmi, A. Stephen K.; Lothschuetz, Christian; Ackermann, Martin; Doepp, Rene; Anantharaman, Sankaran; Marchetti, Benjamin; Bertagnolli, Helmut; Rominger, Frank Chemistry - A European Journal, 2010 , vol. 16, # 27 p. 8012 - 8019

~%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Chiou, Shyh-Ying; Cheng, Yu-Ru; Lu, Chun-Ping; Lin, Yan-Fu; Lin, Long-Yau; Lin, Gialih JAOCS, Journal of the American Oil Chemists' Society, 2006 , vol. 83, # 3 p. 201 - 207

~%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Drake; Melamed Patent: US2627489 , 1949 ;

~0%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Mella, Mariella; Freccero, Mauro; Albini, Angelo Journal of Organic Chemistry, 1994 , vol. 59, # 5 p. 1047 - 1052

~%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Chiou, Shyh-Ying; Cheng, Yu-Ru; Lu, Chun-Ping; Lin, Yan-Fu; Lin, Long-Yau; Lin, Gialih JAOCS, Journal of the American Oil Chemists' Society, 2006 , vol. 83, # 3 p. 201 - 207

~%

Hexanoic acid,2-hydroxyethyl ester Structure

Hexanoic acid,2...

CAS#:6946-90-3

Literature: Etlis,V.S. et al. Journal of Organic Chemistry USSR (English Translation), 1970 , vol. 6, p. 460 - 462 Zhurnal Organicheskoi Khimii, 1970 , vol. 6, # 3 p. 459 - 462

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Synonyms

Capronsaeure-<2-hydroxy-aethylester>
2-Hydroxyethyl hexanoate
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