(1-Methyl-1H-pyrrol-2-yl)methanamine

Modify Date: 2024-01-10 19:07:34

(1-Methyl-1H-pyrrol-2-yl)methanamine Structure
(1-Methyl-1H-pyrrol-2-yl)methanamine structure
Common Name (1-Methyl-1H-pyrrol-2-yl)methanamine
CAS Number 69807-81-4 Molecular Weight 110.157
Density 1.0±0.1 g/cm3 Boiling Point 199.6±15.0 °C at 760 mmHg
Molecular Formula C6H10N2 Melting Point N/A
MSDS N/A Flash Point 74.5±20.4 °C

 Names

Name (1-methylpyrrol-2-yl)methanamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 199.6±15.0 °C at 760 mmHg
Molecular Formula C6H10N2
Molecular Weight 110.157
Flash Point 74.5±20.4 °C
Exact Mass 110.084396
PSA 30.95000
LogP 0.08
Vapour Pressure 0.3±0.4 mmHg at 25°C
Index of Refraction 1.536
Storage condition 2-8°C

 MSDS

Name: (1-Methyl-1H-pyrrol-2-yl)methylamine 97% Material Safety Data Sheet
Synonym:
CAS: 69807-81-4
Section 1 - Chemical Product MSDS Name:(1-Methyl-1H-pyrrol-2-yl)methylamine 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
69807-81-4 (1-Methyl-1H-pyrrol-2-yl)methylamine 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 69807-81-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Viscous liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 53 - 57 deg C @0.5mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H10N2
Molecular Weight: 110

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, halogens, halogenated agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 69807-81-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(1-Methyl-1H-pyrrol-2-yl)methylamine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 69807-81-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 69807-81-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 69807-81-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

RIDADR UN 2735
HS Code 2933990090

 Synthetic Route

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(1-Methyl-1H-pyrrol-2-yl)methanamine Structure

(1-Methyl-1H-py...

CAS#:69807-81-4

Literature: Journal of Medicinal Chemistry, , vol. 44, # 26 p. 4505 - 4508

~%

(1-Methyl-1H-pyrrol-2-yl)methanamine Structure

(1-Methyl-1H-py...

CAS#:69807-81-4

Literature: Morikawa; Honda; Endoh; Matsumoto; Akamatsu; Mitsui; Koizumi Chemical and Pharmaceutical Bulletin, 1990 , vol. 38, # 4 p. 930 - 935

~%

(1-Methyl-1H-pyrrol-2-yl)methanamine Structure

(1-Methyl-1H-py...

CAS#:69807-81-4

Literature: Journal of Medicinal Chemistry, , vol. 38, # 21 p. 4198 - 4210

~%

(1-Methyl-1H-pyrrol-2-yl)methanamine Structure

(1-Methyl-1H-py...

CAS#:69807-81-4

Literature: Journal of Medicinal Chemistry, , vol. 38, # 21 p. 4198 - 4210

~%

(1-Methyl-1H-pyrrol-2-yl)methanamine Structure

(1-Methyl-1H-py...

CAS#:69807-81-4

Literature: Tetrahedron, , vol. 54, # 10 p. 2021 - 2030

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

1-(1-Methyl-1H-pyrrol-2-yl)methanamine
(1-methyl-1H-pyrrol-2-yl)aminomethane
2-aminomethyl-1-methyl-1H-pyrrole
1H-Pyrrole-2-methanamine, 1-methyl-
(1-methyl-1H-pyrrol-2-yl)methanamine
2-(3-BUTOXYPHENYL)-7-CHLORO-8-METHYLQUINOLINE-4-CARBOXYLIC ACID
C-(1-methyl-1H-pyrrol-2-yl)methylamine
F2169-1279
(1-Methyl-1H-Pyrrol-2-Yl)Methylamine
2-(1-methyl)pyrrolylmethyl amine
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