1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester

Modify Date: 2024-01-08 10:21:47

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure
1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester structure
Common Name 1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester
CAS Number 941-43-5 Molecular Weight 188.22100
Density 1.046g/cm3 Boiling Point 228.1ºC at 760mmHg
Molecular Formula C9H16O4 Melting Point N/A
MSDS N/A Flash Point 91.1ºC

 Names

Name ethyl 3-(2-methyl-1,3-dioxolan-2-yl)propanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.046g/cm3
Boiling Point 228.1ºC at 760mmHg
Molecular Formula C9H16O4
Molecular Weight 188.22100
Flash Point 91.1ºC
Exact Mass 188.10500
PSA 44.76000
LogP 1.09270
Index of Refraction 1.432

 MSDS

Version 1.1
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product NameETHYL 2-METHYL-1,3-DIOXOLANE-2 - 50 MG
-PROPIONATE

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Not hazardous according to Directive 67/548/EEC.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
ETHYL941-43-5 213-379-4 None
2-METHYL-1,3-DIOXOLANE-2-PROPIONAT
E
FormulaC9H16O4
Molecular Weight 188,2200 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

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5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Avoid inhalation. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Respiratory protection is not required. Where
protection from nuisance levels of dusts are desired, use type N95
(US) or type P1 (EN 143) dust masks.
Hand Protection: Protective gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

AppearancePhysical State: Liquid
PropertyValueAt Temperature or Pressure
pHN/A
BP/BP RangeN/A
MP/MP RangeN/A
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Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
Partition Coefficient Log Kow: 1,114
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SENSITIZATION
Sensitization: Possible sensitizer.
Skin: Prolonged or repeated exposure may cause allergic
reactions in certain sensitive individuals. The preceding data,
or interpretation of data, was determined using Quantitative
Structure Activity Relationship (QSAR) modeling.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.

12 - Ecological Information

No data available.

13 - Disposal Considerations

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SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.

15 - Regulatory Information

Not hazardous according to Directive 67/548/EEC.

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2932999099

 Synthetic Route

~99%

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure

1,3-Dioxolane-2...

CAS#:941-43-5

Literature: THE UNIVERSITY OF BRITISH COLUMBIA Patent: WO2004/54957 A2, 2004 ; Location in patent: Page 23-24 ;

~98%

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure

1,3-Dioxolane-2...

CAS#:941-43-5

Literature: Ogura, Tetsuhiro; Usuki, Toyonobu Tetrahedron, 2013 , vol. 69, # 13 p. 2807 - 2815

~%

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure

1,3-Dioxolane-2...

CAS#:941-43-5

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. <2> 156, p. 103,137

~92%

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure

1,3-Dioxolane-2...

CAS#:941-43-5

Literature: Kanemasa; Otsuka; Doi; Tsuge; Wada Synthesis, 1990 , # 12 p. 1167 - 1169

~%

1,3-Dioxolane-2-propanoicacid, 2-methyl-, ethyl ester Structure

1,3-Dioxolane-2...

CAS#:941-43-5

Literature: Journal of the Chemical Society, , p. 3972,3978

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

ETHYL 3-(2-METHYL-[1,3]DIOXOLAN-2-YL)PROPANOATE
1,3-Dioxolane-2-propionic acid,2-methyl-,ethyl ester
ethyl levulineate ethylene acetal
Ethyl 2-methyl-1,3-dioxolane-2-propionate
ethyl levulinate 4-ethylene acetal
2-[2'-(ethoxycarbonyl)ethyl]-2-methyldioxolane
2-methyl-1,3-dioxolane-2-propanoic acid ethyl ester
ethyl 4,4-ethylenedioxypentanoate
3-(2-methyl-[1,3]dioxolan-2-yl)-propionic acid ethyl ester
1,3-Dioxolane-2-propanoic acid,2-methyl-,ethyl ester