The active role of NHC ligands in platinum-mediated tandem hydroboration–cross coupling reactions

…, JA Mata, AM Segarra, E Peris, E Fernandez

Index: Lillo, Vanesa; Mata, Jose A.; Segarra, Anna M.; Peris, Eduardo; Fernandez, Elena Chemical Communications, 2007 , # 21 p. 2184 - 2186

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Citation Number: 20

Abstract

The catalytic insertion of unsaturated moieties into a B–H bond through the hydroboration protocol is an effective strategy for selectively obtaining organoboron derivatives, 1 an important class of compounds used as synthetic intermediates 2 especially for constructing carbon frameworks. 3 Although hydroboration can also be performed under non-catalytic conditions, the search for optimised selectivity on the target organoborane compounds ...

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