Monatshefte für Chemie/Chemical Monthly

Beiträge zur Konformationsanalyse der Aryl—Methoxy-Bindung

O Hofer

Index: Hofer,O. Monatshefte fuer Chemie, 1978 , vol. 109, p. 405 - 419

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Citation Number: 11

Abstract

Abstract The lanthanide induced shifts of a series of methoxy-indanones and-indanols were recorded and interpreted in terms of hindered rotation about the aryl—methoxy bond. A planar conformation was found in all cases, the populations of the two planar positions being determined by the substituent ortho to the methoxyl group. Some of the compounds are very suitable for NOE experiments; these measurements supported the LIS results. ...