Iron (II)-catalyzed amidation of aldehydes with iminoiodinanes at room temperature and under microwave-assisted conditions

TMU Ton, C Tejo, S Tania, JWW Chang…

Index: Ton, Thi My Uyen; Tejo, Ciputra; Tania, Stefani; Chang, Joyce Wei Wei; Chan, Philip Wai Hong Journal of Organic Chemistry, 2011 , vol. 76, # 12 p. 4894 - 4904

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Citation Number: 31

Abstract

A method for the amidation of aldehydes with PhI NTs/PhI NNs as the nitrogen source and an inexpensive iron (II) chloride+ pyridine as the in situ formed precatalyst under mild conditions at room temperature or microwave assisted conditions is described. The reaction was operationally straightforward and accomplished in moderate to excellent product yields (20–99%) and with complete chemoselectivity with the new C–N bond forming only at the ...

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