Copper catalyzed oxidation of organozinc halides

…, DT Blackwell, K Tanaka, DR Spring

Index: Su, Xianbin; Fox, David J.; Blackwell, David T.; Tanaka, Kiyotaka; Spring, David R. Chemical Communications, 2006 , # 37 p. 3883 - 3885

Full Text: HTML

Citation Number: 17

Abstract

Organocuprates, often used in conjugate addition, epoxide opening, halide displacement and carbocupration, 6 have a relatively high-lying HOMO, which means that carbon–carbon bond synthesis by organocuprate oxidation is a relatively easy process. The oxidation of lithium organocuprates 7,8 has been handicapped, however, by the poor functional group tolerance of the organolithium precursors. We have recently shown that the functional group tolerance can be improved ...

Related Articles:

Reductive coupling of benzyl halides using nickel (0)-complex generated in situ in the presence of tetraethylammonium iodide, a simple and convenient synthesis of …

[Iyoda, Masahiko; Sakaitani, Masahiro; Otsuka, Hiroki; Oda, Masaji Chemistry Letters, 1985 , p. 127 - 130]

Flash pyrolysis of 4-methylene-1, 2, 3-benzotriazines

[Noyce, S. J.; Randles, K. R.; Storr, R. C. Tetrahedron Letters, 1985 , vol. 26, # 7 p. 941 - 944]

THE COUPLING ACTION OF THE GRIGNARD REAGENT I. THE ORTHO-AND PARA-CYANOBENZYL HALIDES

[Fuson Journal of the American Chemical Society, 1926 , vol. 48, p. 834]

THE COUPLING ACTION OF THE GRIGNARD REAGENT I. THE ORTHO-AND PARA-CYANOBENZYL HALIDES

[Fuson Journal of the American Chemical Society, 1926 , vol. 48, p. 834]

THE COUPLING ACTION OF THE GRIGNARD REAGENT I. THE ORTHO-AND PARA-CYANOBENZYL HALIDES

[Fuson Journal of the American Chemical Society, 1926 , vol. 48, p. 834]

More Articles...