Journal of Organometallic Chemistry

Synthese und eigenschaften von bis (dialkylamino)-perfluormethylphosphinen und-arsinen

O Adler, F Kober

Index: Adler,O.; Kober,F. Journal of Organometallic Chemistry, 1974 , vol. 72, p. 351 - 360

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Abstract

Abstract The reaction of the perfluoromethyl compounds CF 3 PI 2 and CF 3 AsI 2 with secondary amines HNR 2 yield the bis (dialkylamino) perfluoromethylphosphines and- arsines CF 3 P (NR 2) 2 and CF 3 As (NR 2) 2. The IR and NMR spectra are reported and discussed. The cleavage of the P N or As N bond with acid molecules is described.

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