Tetrahedron

Preparation of π-deficient heteroarylzinc halides by oxidative addition of active zinc and its palladium-catalyzed reaction

T Sakamoto, Y Kondo, N Murata, H Yamanaka

Index: Sakamoto, Takao; Kondo, Yoshinori; Murata, Naoko; Yamanaka, Hiroshi Tetrahedron, 1993 , vol. 49, # 43 p. 9713 - 9720

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Citation Number: 73

Abstract

The oxidative addition of active zinc to iodo-and bromo-substituted π-deficient heteroarenes such as pyridine, pyrimidine, and quinoline gave the corresponding heteroarylzinc halides which were transformed to the arylated and benzoylated derivatives by palladium-catalyzed reaction.

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