The Journal of Organic Chemistry

Mercury in organic chemistry. V. Direct esterification of alkyl halides

RC Larock

Index: Larock,R.C. Journal of Organic Chemistry, 1974 , vol. 39, p. 3721 - 3727

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Citation Number: 31

Abstract

The direct esterification of alkyl halides using stoichiometric amounts of sodium, mercury, and silver carboxylates is examined. Treatment of unhindered primary alkyl iodides and bromides, as well as allyl and benzyl chloride, bromide, and iodide, with sodium acetate in HMPA at room temperature provides excellent yields of the corresponding esters. Mercuric acetate in diglyme will react directly only with tert-butyl halides, allyl iodide, and benzyl ...

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