Remote dianions. 3. Novel synthesis of substituted 2-piperidones from imines

CM Thompson, DLC Green…

Index: Thompson, Charles M.; Green, Diana L. C.; Kubas, Robert Journal of Organic Chemistry, 1988 , vol. 53, # 22 p. 5389 - 5390

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Citation Number: 13

Abstract

Sir: Imines have been relatively under utilized (yet easily prepared2 ) functional groups in the synthesis of hetero- cycles. Recently, certain derivatives of imines have been employed in cycloaddition chemi~try,~ and addition reac- tions to the imine moiety have been reported4 (primarily via activation with Lewis acids), opening new opportunities for the construction of aza heterocyclic compounds. In- deed, an intramolecular extension of this latter process

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