Solvomercuration-demercuration. 11. Alkoxymercuration-demercuration of representative alkenes in alcohol solvents with the mercuric salts acetate, trifluoroacetate, …

…, JT Kurek, MH Rei, KL Thompson

Index: Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L. Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2551 - 2557

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Citation Number: 24

Abstract

The alkoxymercuration-demercuration of seven representative olefins with the mercuric salts acetate, trifluoroacetate, nitrate, and methanesulfonate, in methyl, ethyl, isopropyl, and tert- butyl alcohols was examined. Mercuric acetate was effective only in methanol and ethanol. On the other hand, mercuric trifluoroacetate was effective in all four solvents, giving in most cases high yields of the corresponding ethers. Both mercuric nitrate and mercuric ...

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