Oxidation of mandelic acid by Fenton's reagent

C Walling, K Amarnath

Index: Walling, Cheves; Amarnath, Kalyani Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1185 - 1189

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Citation Number: 89

Abstract

Abstract: Mandelic acid forms a stable 1: l complex with Fe2'at pH 1-3. Its oxidation by H202 and S20g2-has been investigated in the hope of detecting intramolecular oxidation- reduction of any intermediate Fe"'species, rather than the usual hydroxyl radical process. Products are benzaldehyde and hydroxymandelic acids, consistent with either, but added hydroxyl radical trapsacetone or crotonic acid-are able to intercept only about half of the ...