Formation of synthetically useful camphor derivatives: mechanistic aspects

WM Dadson, JH Hutchinson…

Index: Dadson, William M.; Hutchinson, John H.; Money, Thomas Canadian Journal of Chemistry, 1990 , vol. 68, # 10 p. 1821 - 1828

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Citation Number: 11

Abstract

Evidence is presented to support the occurrence of a 3, 2-endo-methyl shift during the C (8)- bromination of 3, 3-dibromocamphor. The mechanism proposed for the rearrangement of (+)- 3-bromocamphor to (-)-6-bromocamphor is also supported by experimental evidence. Key words: 8-bromocamphor, 6-bromocamphor, 3, 2-endo methyl shifts.

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