Tetrahedron

Synthesis of 3-and 4-substituted cyclic α-amino acids structurally related to ACPD

F Alonso, I Micó, C Nájera, JM Sansano, M Yus…

Index: Alonso, Francisco; Mico, Irene; Najera, Carmen; Sansano, Jose M.; Yus, Miguel; et al. Tetrahedron, 1995 , vol. 51, # 37 p. 10259 - 10280

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Citation Number: 18

Abstract

The preparation of 3-substituted cyclopentanones 12-16, 4-substituted cyclohexanones 23– 28 and cycloheptanones 38–41 is described. Substituents in the cycloalkanones are carboxylate, phosphonate or tetrazole groups, separated from the ring by a 0, 1, 2, or 3 carbon atoms chain. These cycloalkanones have been transformed into α-amino acids 9–11 by hydrolysis of the corresponding hydantoin derivatives 21, 37 and 62, obtained under ...

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