Journal of organometallic chemistry

Preparation of (η 5-cyclopentadienyl) and (η 5-methylcyclopentadienyl) Fe (CO) 2 Me cyclodextrin inclusion compounds and their subsequent ligand substitution …

PP Patel, ME Welker

Index: Patel, Paren P.; Welker, Mark E. Journal of Organometallic Chemistry, 1997 , vol. 547, # 1 p. 103 - 112

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Abstract

Two iron complexes,(η5-Cyclopentadienyl) Fe (CO) 2Me and (η5-Methylcyclopentadienyl) Fe (CO) 2Me, were prepared followed by their α, β, and γ cyclodextrin inclusion compounds. The included iron complexes participate in phosphine induced ligand substitution reactions under both thermal and photochemical conditions with no CO insertion/alkyl migration products observed in either case.