Direct synthesis of palladium porphyrins from acyldipyrromethanes

DS Sharada, AZ Muresan…

Index: Imamoto, Tsuneo; Kodera, Masahito; Yokoyama, Masataka Synthesis, 1982 , # 2 p. 134 - 136

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Citation Number: 41

Abstract

... reaction conditions, Pd(0)(PPh 3 ) 4, Pd(II)(CH 3 CN) 2 Cl 2, Na 2 Pd(IV)Cl 6. ... c) 10 with EtMgBr at −78 °C in THF followed by addition of a S-2-pyridyl thioate 17 (Mukaiyama reagent, 5a−e) (Scheme 1). Each Mukaiyama reagent is known, 2,12,17,18 although the synthesis of 5e ...