Free-radical reactions of 3, 3-dimethylbutene, 3-methyl-3-phenylbutene, and tert-pentylbenzene induced by di-tert-butyl peroxide

M Abramovici, H Pines

Index: Abramovici,M.; Pines,H. Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270

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Citation Number: 6

Abstract

The reaction of 3, 3-dimethylbutene with DTBP was carried out in a 125-cc-capacity stainless steel rotating autoclave, heated at 140-150" for 3.5 hr. The autoclave was then cooled, and both liquid and gaseous reaction products were collected and analyzed using a F & J! t Model 720 programmed temperature gas chromatograph. The results are given in Table I. From the data obtained it was calculated that the molar ratio of olefin reacted to ...