Synthesis, Redox Properties, and Electronic Coupling in the Diferrocene Aza-dipyrromethene and azaBODIPY Donor–Acceptor Dyad with Direct Ferrocene− α-Pyrrole …

CJ Ziegler, K Chanawanno, A Hasheminsasab…

Index: Ziegler, Christopher J.; Chanawanno, Kullapa; Hasheminsasab, Abed; Zatsikha, Yuriy V.; Maligaspe, Eranda; Nemykin, Victor N. Inorganic Chemistry, 2014 , vol. 53, # 9 p. 4751 - 4755

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Citation Number: 27

Abstract

The novel diiron 3, 3′-diferrocenylazapyrromethene (3) and its difluoroboron (azaBODIPY) derivative (4) were synthesized and characterized by UV− vis, NMR, electrochemistry, spectroelectrochemistry, and X-ray crystallographic methods, while their spectroscopy and redox behavior were correlated with the density functional theory (DFT) and time-dependent DFT calculations.

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