Tetrahedron

A highly efficient and widely functional-group-tolerant catalyst system for copper (I)-catalyzed S-arylation of thiols with aryl halides

Y Feng, H Wang, F Sun, Y Li, X Fu, K Jin

Index: Feng, Yang; Wang, Huifeng; Sun, Fangfang; Li, Yaming; Fu, Xinmei; Jin, Kun Tetrahedron, 2009 , vol. 65, # 47 p. 9737 - 9741

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Citation Number: 73

Abstract

A mild, general, and efficient copper-catalyzed system for C–S bond formation with high chemoselectivity and wide functional group tolerance is developed. With CuBr as catalyst and 1, 2, 3, 4-tetrahydro-8-hydroxy-quinoline as ligand, the S-arylation of thiols with aryl halides performed well, the activated aryl iodides could take place even at room temperature, and the activated aryl bromides and chlorides give the corresponding ...

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