Reactions with Mercaptans. IV. Reaction of Aromatic Thiols with 3 (2H)-Thianaphthenone-1, 1-dioxides and 2-Benzylidene-3 (2H)-thianaphthenone-1-1-dioxide

A Mustafa, SMAD Zayed

Index: Mustafa; Zayed Journal of the American Chemical Society, 1957 , vol. 79, p. 3500

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Citation Number: 5

Abstract

The condensation reaction of 3 (2H)-thianapht~ ienone-l, l-dioxides (I) with aromatic aldehydes has been investigated, eg, 3 (2N)-thianaphthenone-l, l-dioxide condenses with benzaldehyde to give 2-benzyIidene-3 (2H)-thianaphthenone-l, 1-dioxide (IIa). The latter undergoes an addition reaction with thiophenol, yielding the thiol adduct believed to have structure VI. Aromatic thiols react with 3 (~ 11)-tl~ i~ naphthenone-l, l-dioxides, in the ...

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