A facile conversion of sulfoximines and sulfonediimines to sulfoxides and sulfilimines with tert-butyl nitrite

K Akutagawa, N Furukawa, S Oae

Index: Akutagawa, Kunihiko; Furukawa, Naomichi; Oae, Shigeru Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 369 - 374

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Abstract

KUNIHIKO AKUTAGAWA, NAOMICHI FURUKAWA* and SHIGERU OAE*a ... Department of Chemistry, The University of Tsukuba, Sakura-mura, Niihari-gun, Ibaraki 305, Japan ... N-Unsubstituted sulfoximines and N-mono-tosylsulfonediimines were found to react readily with rerr-butyl nitrite to give the corresponding sulfoxides and N-tosylsulfilimines in high yields with no racemization. ... Interest in the chemistry of the aza analogues' of sulfone such as ...

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