Excimer laser photolysis of group 6 metal carbonyls in the gas phase

Y Ishikawa, CE Brown, PA Hackett…

Index: Ishikawa, Yo-ichi; Brown, Carl E.; Hackett, Peter A.; Rayner, David M. Journal of Physical Chemistry, 1990 , vol. 94, p. 2404 - 2413

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Citation Number: 49

Abstract

The excimer laser photolysis of Mo (CO), in the gas phase has been studied at 351, 308, 248, and 222 nm with laser-based, time-resolved infrared absorption spectroscopy. Results have also been obtained on the 308-and 222-nm photolysis of Cr (CO) 6 and on the 222-nm photolysis of W (CO),, complementing earlier studies and presenting a complete picture of group 6 metal carbonyl ultraviolet photodecomposition. Infrared spectra in the range 1700 ...