Molybdenum-carbon bond dissociation energies in molybdenum hexacarbonyl

JA Ganske, RN Rosenfeld

Index: Ganske, Jane A.; Rosenfeld, Robert N. Journal of Physical Chemistry, 1990 , vol. 94, # 10 p. 4315 - 4318

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Citation Number: 9

Abstract

The pressure dependence of the recombination rate constants for Mo (CO),(n= 3, 4, and 5) with CO has been studied by time-resolved infrared laser absorption spectroscopy. These data, in conjunction with an RRKM model for unimolecular decay of the activated molecules [Mo (CO),]*,[Mo (CO),]*, and [Mo (CO),]*, have allowed the determination of the bond dissociation energies for several of the Mo-C bonds in Mo (CO),. The first Mo-C bond ...