Etude de la télomérisation et de la cotélomérisation du fluorure de vinylidéne (VF 2). Part I. Cotélomérisation du VF 2 avec l'acétate de vinyle et le 2- …

B Boutevin, Y Furet, Y Hervaud, G Rigal

Index: Boutevin, Bernard; Furet, Yves; Hervaud, Yves; Rigal, Gerard Journal of Fluorine Chemistry, 1994 , vol. 69, # 1 p. 11 - 18

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Citation Number: 12

Abstract

Abstract The radical telomerization of vinylidene fluoride (VF 2) and of vinyl acetate (VAc) with 2-hydroxyethylmercaptan, and the radical cotelomerization of both monomers with the same thiol have been investigated. In each case, the chemical structures and the chain lengths have been determined by various methods in order to understand the reactivity and the direction of addition of both monomers. This study indicates a greater reactivity for VAc ...