Helvetica Chimica Acta

Inductive, Hyperconjugative and Frangomeric Effects in the Solvolysis of 1??Substituted 3??Bromoadamantanes. Polar effects IV

W Fischer, CA Grob

Index: Fischer,W.; Grob,C.A. Helvetica Chimica Acta, 1978 , vol. 61, p. 1588 - 1608

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Citation Number: 30

Abstract

Abstract Three kinds of polar substitutent effects are observable in the solvolyses of 1-R- substituted 3-bromoadamantanes (VI). This follows from the relationship between products, rate constants k in 80% ethanol, and the inductive substituent constants σ math image of the substituent R. Alkyl groups and electron-attracting substituents at C (1) control the rate by their inductive effects alone, since logk correlates closely with σ math image. However, ...