Tetrahedron letters

Novel synthesis of 1, 3, 5-triselenanes from aldehydes, and novel generation of selenoaldehydes by fragmentation of 1, 3, 5-triselenanes

Y Takikawa, A Uwano, H Watanabe, M Asanuma…

Index: Takikawa, Yuji; Uwano, Akira; Watanabe, Hiroyuki; Asanuma, Masaki; Shimada, Kazuaki Tetrahedron Letters, 1989 , vol. 30, # 44 p. 6047 - 6050

Full Text: HTML

Citation Number: 28

Abstract

Abstract Reaction of aldehydes with (Me 3 Si) 2 Se in the presence of Lewis acid afforded 1, 3, 5-triselenanes via selenoaldehydes. Novel and convenient generation of selenoaldehydes was also achieved by thermally-or Lewis acid-induced fragmentation of 1, 3, 5-triselenanes.

Related Articles:

A novel synthesis of organic diselenides

[Huang, Zhi-Zhen; Liu, Fei-Yan; Du, Jing-Xing; Huang, Xian Organic Preparations and Procedures International, 1995 , vol. 27, # 4 p. 492 - 494]

Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water

[Zhao, Xiaodan; Yu, Zhengkun; Zeng, Fanlong; Chen, Jinzhu; Wu, Xiaowei; Wu, Sizhong; Xiao, Wen-Jing; Zheng, Zhaoyan Advanced Synthesis and Catalysis, 2005 , vol. 347, # 6 p. 877 - 882]

Synthesis of benzoyl-N-phenylthioureas under microwave irradiation and phase transfer catalysis conditions

[Wang, Jin-Xian; Bai, Lin; Li, Wenbo; Hu, Yulai Synthetic Communications, 2000 , vol. 30, # 2 p. 325 - 332]

Efficient Synthesis of Selenocarbonyl Compounds by Treating Carbonyl Compounds with Bis (1, 5-cyclooctanediylboryl) Selenide.

[Shimada, Kazuaki; Jin, Norikazu; Kawaguchi, Michiko; Dobashi, Kumiko; Nagano, Yumi; Fujimura, Manabu; Kudoh, Eiichi; Kai, Tomonari; Saito, Noboru; Masuda, Jun-Ichi; Iwaya, Masaki; Fujisawa, Hiroyuki; Aoyagi, Shigenobu; Takikawa, Yuji Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 1 p. 197 - 206]

Convenient one-flask synthesis of dialkyl selenides and diselenides via lithium triethylborohydride reduction of Sex

[Gladysz,J.A. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 1204 - 1208]

More Articles...