4-Alkoxycarbonyl-2-(2-pyridyl) thiazoles and their complexes with CuII and CoII. Molecular and crystal structure of copper 4-ethoxycarbonyl-2-(2-pyridyl) thiazole …

…, EK Beloglazkina, VV Frolov, AA Moiseeva…

Index: Majouga; Beloglazkina; Frolov; Moiseeva; Zyk Russian Chemical Bulletin, 2009 , vol. 58, # 4 p. 844 - 850

Full Text: HTML

Citation Number: 1

Abstract

Abstract The first synthesis of ethyl 2-(2-pyridyl) thiazole4-carboxylate (2) and bis [2-(2- pyridylthiazol-4-ylcarbonyloxy) ethyl] disulfide (4) is described. The complexation of compounds 2 and 4 with Cu II, Co II, and Ni II chlorides and perchlorates has been studied. Electrochemical behavior of the ligands and complexes obtained has been investigated by cyclic voltammetry and using rotating disk electrode, which allowed us to confirm the ...